A System of Instruction in the Practical Use of the Blowpipe - Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic Combinations by Anonymous
page 41 of 359 (11%)
page 41 of 359 (11%)
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about half an inch wide. Tin is very susceptible of oxidation, and
therefore deprives oxidized substances of their oxygen very quickly, when heated in contact with them. It is employed in blowpipe analysis, for the purpose of producing in glass beads a lower degree of oxidation, particularly if the substance under examination contains only a small portion of such oxide. These oxides give a characteristic color to the bead, and thus are detected. The bead is heated upon charcoal in the reduction flame, with a small portion of the tin, whereby some of the tin is melted and mixes with the bead. The bead should be reduced quickly in the reduction flame, for by continuing the blast too great a while, the oxide of tin separates the other oxides in the reduced or metallic state, while we only require that they shall only be converted into a sub-oxide, in order that its peculiar color may be recognized in the bead. The addition of too much tin causes the bead to present an unclean appearance, and prevents the required reaction. 11. _Silica_ (SiO^{3}).--This acid does not even expel carbonic acid in the wet way, but in a glowing heat it expels the strongest volatile acids. In blowpipe analysis, we use it fused with carbonate of soda to a bead, as a test for sulphuric acid, and in some cases for phosphoric acid. Also with carbonate of soda and borax, for the purpose of separating tin from copper. Finely powdered quartz will answer these purposes. If it cannot be procured, take well washed white sand and mix it with two parts of carbonate of soda and two parts of carbonate of potassa. Melt the materials together, pound up the cooled mass, dissolve in hot water, filter, add to the filtrate hydrochloric acid, and evaporate to |
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