A System of Instruction in the Practical Use of the Blowpipe - Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic Combinations by Anonymous
page 51 of 359 (14%)
page 51 of 359 (14%)
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There are several metals which will sublime, and may be examined in
the cold portion of the tube. _Mercury_ condenses upon the tube in minute globules. These often do not present the metallic appearance until they are disturbed with a glass rod, when they attract each other, and adhere as small globules. Place in the tube about a grain of red precipitate of the drug stores and apply heat, when the oxide will become decomposed, its oxygen will escape while the vaporized mercury will condense upon the cold portion of the tube, and may there be examined with a magnifying glass. _Arsenic_, when vaporized, may be known by its peculiar alliaceous odor. Arsenic is vaporized from its metallic state, and likewise from its alloys. Several compounds which contain arsenic will also sublime, such as the arsenical cobalt. Place in the bulb a small piece of arsenical cobalt or "fly-stone," and apply heat. The sulphide of arsenic will first rise, but soon the arsenic will adhere to the sides of the tube. The metals tellurium and cadmium are susceptible of solution, but the heat required is a high one. This is best done upon charcoal. The _perchloride of mercury_ sublimes undecomposed in the bulb, previously undergoing fusion. The _protochloride of mercury_ likewise sublimes, but it does not undergo fusion first, as is the case with the corrosive sublimate. The _ammoniacal salts_ all are susceptible of sublimation, which they do without leaving a residue. There are, however, several which contain fixed acids, which latter are left in the bulb. This is |
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