A System of Instruction in the Practical Use of the Blowpipe - Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic Combinations by Anonymous
page 52 of 359 (14%)
page 52 of 359 (14%)
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particularly the case with the phosphates and borates. A piece of red
litmus paper will readily detect the escaping ammonia, while its odor will indicate its presence with great certainty. The halogen compounds of mercury, we should have mentioned, also sublime, the red iodide giving a yellow sublimate. The bulb is also a convenient little instrument for the purpose of heating those substances which phosphoresce, and likewise those salts that decrepitate. Should the above reactions not be readily discerned, it should not be considered as an indication that the substances are not present, for they are frequently expelled in such combinations that the above reactions will not take place. This is often the case with sulphur, selenium, arsenic, and tellurium. It frequently happens, likewise, that these substances are in such combinations that heat alone will not sublime them; or else two or more of them may arise together, and thus complicate the sublimate, so that the eye cannot readily detect either substance. Sometimes sulphur and arsenic will coat the tube with a metal-like appearance, which is deceptive. This coating presents a metallic lustre at its lower portion, but changing, as it progresses upward, to a dark brown, light brown, orange or yellow; this sublimate being due to combinations of arsenic and sulphur, which compounds are volatilized at a lower temperature than metallic arsenic. If certain reagents are mixed with many substances, changes are effected which would not ensue with heat alone. _Formiate of soda_ possesses the property of readily reducing metallic oxides. When this salt is heated, it gives off a quantity of carbonic oxide gas. This |
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