A System of Instruction in the Practical Use of the Blowpipe - Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic Combinations by Anonymous
page 57 of 359 (15%)
page 57 of 359 (15%)
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the eye becomes familiarized with the appearances of their
incrustations upon charcoal. The greater part of the metals fuse when submitted to the heat of the blowpipe, and if exposed to the outer flame, they oxidize. These metals, termed the noble metals, do not oxidize, but they fuse. The metals platinum, iridium, rhodium, osmium and palladium do not fuse. The metal osmium, if exposed to the flame of oxidation, fuses and is finally dissipated as osmic acid. In the latter flame, the salts of the noble metals are reduced to the metallic state, and the charcoal is covered with the bright metal. We shall give a brief description of the appearance of the principal elementary bodies upon being fused with charcoal. This plan is that deemed the most conducive to the progress of the student, by Berzelius, Plattner, and Sherer. Experience has taught us that this method is the most efficient that could have been devised as an initiatory exercise for the student, ere he commences a more concise and methodical method of analysis. In these reactions upon charcoal, we shall follow nearly the language of Plattner and Sherer. SELENIUM is not difficult of fusion, and gives off brown fumes in either the oxidation or reduction flame. The deposit upon the charcoal is of a steel-grey color, with a slightly metallic lustre. The deposit however that fuses outside of this steel-grey one is of a dull violet color, shading off to a light brown. Under the flame of oxidation this deposit is easily driven from one portion of the charcoal to another, while the application of the reducing flame volatilizes it with the evolution of a beautiful blue light. The characteristic odor of decayed horse-radish distinguishes the volatilization of this metal. |
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