A System of Instruction in the Practical Use of the Blowpipe - Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic Combinations by Anonymous
page 61 of 359 (16%)
page 61 of 359 (16%)
![]() | ![]() |
|
incrusts the charcoal, at a small distance from the assay, with
molybdic acid, which, near the assay, forms transparent crystalline scales, and is elsewhere deposited as a fine powder. The incrustation, while hot, is of a yellow color, but becomes white after cooling. It may be volatilized by heating with either flame, and leaves the surface of the charcoal, when perfectly cooled, of a dark-red copper color, with a metallic lustre, due to the oxide of molybdenum, which has been formed by the reducing action of the charcoal upon the molybdic acid. In the reducing flame, metallic molybdenum remains unchanged. SILVER.--This metal, when fused alone, and kept in this state for some time, under a strong oxidizing flame, covers the charcoal with a thin film of dark reddish-brown oxide. If the silver be alloyed with lead, a yellow incrustation of the oxide of that metal is first formed, and afterwards, as the silver becomes more pure, a dark red deposit is formed on the charcoal beyond. If the silver contains a small quantity of antimony, a white incrustation of antimonious acid is formed, which becomes red on the surface if the blast be continued. And if lead and antimony are both present in the silver, after the greater part of these metals have been volatilized, a beautiful crimson incrustation is produced upon the charcoal. This result is sometimes obtained in fusing rich silver ores on charcoal. SULPHIDES, CHLORIDES, IODIDES, AND BROMIDES. In blowpipe experiments, it rarely occurs that we have to deal with pure metals, which, if not absolutely non-volatile, are recognized by the incrustation they form upon charcoal. Some compound substances, |
|