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A System of Instruction in the Practical Use of the Blowpipe - Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic Combinations by Anonymous
page 62 of 359 (17%)
when heated upon charcoal, form white incrustations, resembling that
formed by antimony, and which, when heated, may, in like manner, be
driven from place to place. Among these are certain sulphides, as
sulphide of potassium, and sulphide of sodium, which are formed by the
action of the reducing flame upon the sulphates of potassa and soda,
and are, when volatilized, reconverted into those sulphates, and as
such deposited on the charcoal. No incrustation is, however, formed,
until the whole of the alkaline sulphate has been absorbed into the
charcoal, and has parted with its oxygen. As sulphide of potassium is
more volatile than sulphide of sodium, an incrustation is formed from
the former sooner than from the latter of these salts, and is
considerably thicker in the former case. If the potash incrustation be
touched with the reducing flame, it disappears with a violet-colored
flame; and if a soda incrustation be treated in like manner, an
orange-yellow flame is produced.

Sulphide of lithium, formed by heating the sulphate in the reducing
flame, is volatilized in similar manner by a strong blast, although
less readily than the sulphide of sodium. It affords a greyish white
film, which disappears with a crimson flame when submitted to the
reducing flame.

Besides the above, the sulphides of bismuth and lead give, when heated
in either flame, two different incrustations, of which the more
volatile is of a white color, and consists in the one case of sulphate
of lead, and in the other of sulphate of bismuth. If either of these
be heated under the reducing flame, it disappears in the former case
with a bluish flame, in the latter unaccompanied by any visible flame.
The incrustation formed nearest to the assay consists of the oxide of
lead or bismuth, and is easily recognized by its color when hot and
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