A System of Instruction in the Practical Use of the Blowpipe - Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic Combinations by Anonymous
page 62 of 359 (17%)
page 62 of 359 (17%)
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when heated upon charcoal, form white incrustations, resembling that
formed by antimony, and which, when heated, may, in like manner, be driven from place to place. Among these are certain sulphides, as sulphide of potassium, and sulphide of sodium, which are formed by the action of the reducing flame upon the sulphates of potassa and soda, and are, when volatilized, reconverted into those sulphates, and as such deposited on the charcoal. No incrustation is, however, formed, until the whole of the alkaline sulphate has been absorbed into the charcoal, and has parted with its oxygen. As sulphide of potassium is more volatile than sulphide of sodium, an incrustation is formed from the former sooner than from the latter of these salts, and is considerably thicker in the former case. If the potash incrustation be touched with the reducing flame, it disappears with a violet-colored flame; and if a soda incrustation be treated in like manner, an orange-yellow flame is produced. Sulphide of lithium, formed by heating the sulphate in the reducing flame, is volatilized in similar manner by a strong blast, although less readily than the sulphide of sodium. It affords a greyish white film, which disappears with a crimson flame when submitted to the reducing flame. Besides the above, the sulphides of bismuth and lead give, when heated in either flame, two different incrustations, of which the more volatile is of a white color, and consists in the one case of sulphate of lead, and in the other of sulphate of bismuth. If either of these be heated under the reducing flame, it disappears in the former case with a bluish flame, in the latter unaccompanied by any visible flame. The incrustation formed nearest to the assay consists of the oxide of lead or bismuth, and is easily recognized by its color when hot and |
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