Scientific American Supplement, No. 443, June 28, 1884 by Various
page 25 of 107 (23%)
page 25 of 107 (23%)
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the ethereal solution is allowed to evaporate. The residue (phenol) is
weighed directly, and from this the percentage can be ascertained. By this method of extraction, the oil of turpentine, resins, etc., contained in _Pinus sylvestris_ do not pass into solution, because they are insoluble in water, even when boiling; what passes into solution besides phenol is a little tannin, which is practically insoluble in ether. From this investigation it will be seen that phenol exists in various proportions in the free state in the leaves, stem, and cones of _Pinus sylvestris_, and as this compound is a product in the distillation of coal, and as geologists have to a certain extent direct evidence that the flora of the Carboniferous epoch was essentially crytogamous, the only phænogamous plants which constituted any feature in "the coal forests" being the coniferæ, and as coal is the fossil remains of that gigantic flora which contained phenol, I think my discovery of phenol in the coniferæ of the present day further supports, from a chemical point of view, the views of geologists that the coniferæ existed so far back in the world's history as the Carboniferous age. I think this discovery also supports the theory that the origin of petroleum in nature is produced by moderate heat on coal or similar matter of a vegetable origin. For we know from the researches of Freund and Pebal (_Ann. Chem. Pharm._, cxv. 19), that petroleum contains phenol and its homologues, and as I have found this organic compound in the coniferæ of to-day, it is probable that petroleum in certain areas has been produced from the conifers and the flora generally of some primæval forests. It is stated by numerous chemists that "petroleum almost always contains solid paraffin" and similar hydrocarbons. Professors Schorlemmer and Thorpe have found heptane in |
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