History and Practice of the Art of Photography by Henry Hunt Snelling
page 33 of 134 (24%)
page 33 of 134 (24%)
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In its Photographic application, the nitrate of silver is the most valuable of the salts of that metal, as from it most of the other argentine compounds can be prepared, although it is not of itself sufficiently sensible to light to render it of much use. CHLORIDE OF SILVER.--This salt of silver, whether in its precipitated state, or when fused, changes its color to a fine bluish grey by a very short exposure to the sun's rays. If combined with a small quantity of nitrate, the change is more rapid, it attains a deep brown, then slowly passes into a fine olive, and eventually, after a few weeks, the metalic silver is seen to be revived on the surface of the salt. Great differences of color are produced on chlorides of silver precipitated by different muriates. Nearly every variety in combination with the nitrate, becomes at last of the same olive color, the following examples, therefore, have reference to a few minutes exposure, only, to good sunshine; it must also be recollected that the chloride of silver in these cases is contaminated with the precipitant. Muriate of ammonia precipitates chloride to darken to a fine chocolate brown, whilst muriate of lime produces a brick-red color. Muriates of potash and soda afford a precipitate, which darkens speedly to a pure dark brown, and muriatic acid, or aqueous chlorine, do not appear to increase the darkening power beyond the lilac to which the pure chloride of silver changes by exposure. This difference of color appears to be owing to the admixture of the earth or alkali used with the silver salt. |
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