Scientific American Supplement, No. 611, September 17, 1887 by Various
page 45 of 143 (31%)
page 45 of 143 (31%)
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explained to us. We look upon the new process as such a spirited
attempt to turn the tide of a long and losing battle, and as so very interesting on its own merits, that an account of it in these pages will be thoroughly in place. The main idea of the process is to combine the "Leblanc" and the "ammonia-soda" manufacture. But in place of using caustic lime to decompose the ammonium chloride and get back the ammonia, the "alkali waste" spoken of above is employed, it being found that not only is the ammonia driven off, but that also the sulphur in the "waste" is obtained in a form allowing of its easy utilization, it and the ammonia combining to form ammonium sulphide, which passes over in gaseous form from the decomposing apparatus. This ammonium sulphide is, as we shall see, quite as available for the working of the ammonia-soda manufacture as pure and simple ammonia, and all the sulphur can be obtained from it. In outline the process is as follows: We will suppose that a quantity of bicarbonate of sodium has been just precipitated from a brine solution, and we have the residual ammonium chloride to deal with. This is decomposed by "alkali waste," giving a final liquor of calcium chloride, which is run to waste, and a quantity of ammonium sulphide gas. This latter is led at once into a solution of salt in water, till saturation takes place. Into this liquor of brine and ammonium sulphide _pure_ carbonic acid gas is now passed. The ammonium sulphide is decomposed, pure sulphureted hydrogen gas is given off, which is conducted to a gas holder and stored, while ammonium bicarbonate is formed in the liquor, which brings about the conversion of the salt into bicarbonate of sodium, ready for removal and preparation for the market. |
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