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Scientific American Supplement, No. 611, September 17, 1887 by Various
page 45 of 143 (31%)
explained to us. We look upon the new process as such a spirited
attempt to turn the tide of a long and losing battle, and as so very
interesting on its own merits, that an account of it in these pages
will be thoroughly in place.

The main idea of the process is to combine the "Leblanc" and the
"ammonia-soda" manufacture. But in place of using caustic lime to
decompose the ammonium chloride and get back the ammonia, the "alkali
waste" spoken of above is employed, it being found that not only is
the ammonia driven off, but that also the sulphur in the "waste" is
obtained in a form allowing of its easy utilization, it and the
ammonia combining to form ammonium sulphide, which passes over in
gaseous form from the decomposing apparatus. This ammonium sulphide
is, as we shall see, quite as available for the working of the
ammonia-soda manufacture as pure and simple ammonia, and all the
sulphur can be obtained from it.

In outline the process is as follows: We will suppose that a quantity
of bicarbonate of sodium has been just precipitated from a brine
solution, and we have the residual ammonium chloride to deal with.
This is decomposed by "alkali waste," giving a final liquor of calcium
chloride, which is run to waste, and a quantity of ammonium sulphide
gas. This latter is led at once into a solution of salt in water, till
saturation takes place. Into this liquor of brine and ammonium
sulphide _pure_ carbonic acid gas is now passed. The ammonium sulphide
is decomposed, pure sulphureted hydrogen gas is given off, which is
conducted to a gas holder and stored, while ammonium bicarbonate is
formed in the liquor, which brings about the conversion of the salt
into bicarbonate of sodium, ready for removal and preparation for the
market.
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