Scientific American Supplement, No. 611, September 17, 1887 by Various
page 46 of 143 (32%)
page 46 of 143 (32%)
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It will be observed that we printed the word _pure_ in italics in speaking of the carbonic acid used. This is one of the great points in the process, as in order that the sulphureted hydrogen gas obtained shall be concentrated and pure, only pure carbonic acid can be used in liberating it. The apparatus employed in its preparation is perhaps the most ingenious part of the works, and well worthy of attention by others besides alkali makers. The method is based on the fact that if dilute impure carbonic acid is passed into a solution of carbonate of sodium, the carbonic acid is absorbed, bicarbonate of sodium being formed, and the diluting gases passing away. The bicarbonate of sodium on heating gives up the extra carbonic acid, which can be collected and stored pure, while the liquor passes back to simple carbonate of sodium, to be used over again as an absorbent. This is not at all new in theory, of course, nor is this the first proposal to use it commercially; but it is claimed that this is the first successful working of it on a large scale. The gases from a large limekiln supply the dilute carbonic acid gas, which contains 25 per cent. to 30 per cent. of pure gas, the principal diluting gas being, of course, nitrogen. This kiln gas is drawn from the kiln by a blowing engine, and is first cooled in two large receivers. It is then forced into the solution of sodium carbonate in the absorption tower, 65 ft. high by 6 ft. diameter, filled with the liquor. The tower has many diaphragms and perforated "mushrooms," to cause a proper dispersion of the gases as they ascend through the liquor. The strength of liquor found best adapted for the work is equal to a density of about 30° Twaddell. After saturation the mud of bicarbonate of sodium is drawn off and passed into the "decomposer," a |
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