Creative Chemistry - Descriptive of Recent Achievements in the Chemical Industries by Edwin E. Slosson
page 34 of 299 (11%)
page 34 of 299 (11%)
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NN + OO --> NO + NO nitrogen oxygen nitric oxide The --> represents Jove's thunderbolt, a stroke of artificial lightning. We see on the left the molecules of oxygen and nitrogen, before taking the electric treatment, as separate elemental pairs, and then to the right of the arrow we find them as compound molecules of nitric oxide. This takes up another atom of oxygen from the air and becomes NOO, or using a subscript figure to indicate the number of atoms and so avoid repeating the letter, NO_{2} which is the familiar nitro group of nitric acid (HO--NO_{2}) and of its salts, the nitrates, and of its organic compounds, the high explosives. The NO_{2} is a brown and evil-smelling gas which when dissolved in water (HOH) and further oxidized is completely converted into nitric acid. The apparatus which effects this transformation is essentially a gigantic arc light in a chimney through which a current of hot air is blown. The more thoroughly the air comes under the action of the electric arc the more molecules of nitrogen and oxygen will be broken up and rearranged, but on the other hand if the mixture of gases remains in the path of the discharge the NO molecules are also broken up and go back into their original form of NN and OO. So the object is to spread out the electric arc as widely as possible and then run the air through it rapidly. In the Schönherr process the electric arc is a spiral flame twenty-three feet long through which the air streams with a vortex motion. In the Birkeland-Eyde furnace there is a series of semi-circular arcs spread out by the repellent force of a powerful electric magnet in a flaming disc seven feet in diameter with a temperature of 6300° F. In the Pauling furnace the electrodes between which the current strikes |
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