The Chemistry of Hat Manufacturing - Lectures Delivered Before the Hat Manufacturers' Association by Watson Smith
page 24 of 178 (13%)
page 24 of 178 (13%)
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escapes, turns the red litmus paper blue, possesses the smell like
hartshorn, and produces, with hydrochloric acid on the stopper of a bottle, dense white fumes of sal-ammoniac (ammonium chloride). Hence silk contains nitrogen. Thirdly, I will heat some fur with soda-lime. Ammonia escapes, giving all the reactions described under silk. Hence fur, wool, etc., contain nitrogen. As regards proofs of all three of these classes of fibres containing carbon, hydrogen, and oxygen, the char they all leave behind on heating in a closed vessel is the carbon itself present. For the hydrogen and oxygen, a perfectly dry sample of any of these fabrics is taken, of course in quantity, and heated strongly in a closed vessel furnished with a condensing worm like a still. You will find all give you water as a condensate--the vegetable fibre, acid water; the animal fibres, alkaline water from the ammonia. The presence of water proves both hydrogen and oxygen, since water is a compound of these elements. If you put a piece of potassium in contact with the water, the latter will at once decompose, the potassium absorbing the oxygen, and setting free the hydrogen as gas, which you could collect and ignite with a match, when you would find it would burn. That hydrogen was the hydrogen forming part of your cotton, silk, or wool, as the case might be. We must now attack the question of sulphur. First, we prepare a little alkaline lead solution (sodium plumbate) by adding caustic soda to a solution of lead acetate or sugar of lead, until the white precipitate first formed is just dissolved. That is one of our reagents; the other is a solution of a red-coloured salt called nitroprusside of sodium, made by the action of nitric acid on sodium ferrocyanide (yellow prussiate). The first-named is very sensitive to sulphur, and turns black directly. To show this, we take a quantity of flowers of sulphur, dissolve in caustic soda, and add to the lead solution. It turns black at once, because the sulphur unites with the lead to form black sulphide of lead. The nitroprusside, however, |
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