The Chemistry of Hat Manufacturing - Lectures Delivered Before the Hat Manufacturers' Association by Watson Smith
page 25 of 178 (14%)
page 25 of 178 (14%)
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gives a beautiful crimson-purple coloration. Now on taking a little
cotton and heating with the caustic alkaline lead solution, if sulphur were present in that cotton, the fibre would turn black or brown, for the lead would at once absorb such sulphur, and form in the fibre soaked with it, black sulphide of lead. No such coloration is formed, so cotton does not contain sulphur. Secondly, we must test silk. Silk contains nitrogen, like wool, but does it contain sulphur? The answer furnished by our tests is--no! since the fibre is not coloured brown or black on heating with the alkaline lead solution. Thirdly, we try some white Berlin wool, so that we can easily see the change of colour if it takes place. In the hot lead solution the wool turns black, lead sulphide being formed. On adding the nitroprusside solution to a fresh portion of wool boiled with caustic soda, to dissolve out the sulphur, a splendid purple coloration is produced. Fur and hair would, of course, do the same thing. Lead solutions have been used for dyeing the hair black; not caustic alkaline solutions like this, however. They would do something more than turn the hair black--probably give rise to some vigorous exercise of muscular power! Still it has been found that even the lead solutions employed have, through gradual absorption into the system, whilst dyeing the hair black, also caused colics and contractions of the limbs. Having now found means for proving the presence of the various elements composing cotton, silk, and wool, fur or hair, we come to methods that have been proposed for distinguishing these fibres more generally, and for quantitatively determining them in mixtures. One of the best of the reagents for this purpose is the basic zinc chloride already referred to. This is made as follows: 100 parts of fused zinc chloride, 85 parts of water, and 4 parts of zinc oxide are boiled together until a clear solution is obtained. This solution dissolves silk slowly in the cold, |
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