The Chemistry of Hat Manufacturing - Lectures Delivered Before the Hat Manufacturers' Association by Watson Smith
page 41 of 178 (23%)
page 41 of 178 (23%)
|
told you that on boiling, the excess of carbonic acid holding chalk or
carbonate of lime in solution as bicarbonate, is decomposed and carbonate of lime precipitated. You can at once imagine, then, what takes place in your steam boilers when such water is used, and how incrustations are formed. Let us now inquire as to the precise nature of the waste and injury caused by hard and impure waters. Let us also take, as an example, those most commonly occurring injurious constituents, the magnesian and calcareous impurities. Hard water only produces a lather with soap when that soap has effected the softening of the water, and not till then. In that process the soap is entirely wasted, and the fatty acids in it form, with the lime and magnesia, insoluble compounds called lime and magnesia soaps, which are sticky, greasy, adhesive bodies, that precipitate and fix some colouring matters like a mordant. We have in such cases, then, a kind of double mischief--(i) waste of soap, (ii) injury to colours and dyes on the fabrics. But this is not all, for colours are precipitated as lakes, and mordants also are precipitated, and thus wasted, in much the same sense as the soaps are. Now by taking a soap solution, formed by dissolving a known weight of soap in a known volume of water, and adding this gradually to hard water until a permanent lather is just produced, we can directly determine the consumption of soap by such a water, and ascertain the hardness. Such a method is called Clark's process of determination or testing, or Clark's soap test. We hear a great deal just now of soaps that will wash well in hard water, and do wonders under any conditions; but mark this fact, none of them will begin to perform effective duty until such hard water has been rendered soft at the expense of the soap. Soaps made of some oils, such as cocoa-nut oil, for example, are more soluble in water than when made of tallow, etc., and so they more quickly soften a hard water and yield lather, but they are wasted, as far as consumption is concerned, to just the same extent as any other soaps. They do not, |
|