The Chemistry of Hat Manufacturing - Lectures Delivered Before the Hat Manufacturers' Association by Watson Smith
page 43 of 178 (24%)
page 43 of 178 (24%)
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the lime, thus weakening the mordant baths.
_Ferruginous Impurities in Water._--Iron in solution in water is very objectionable in dyeing operations. When the iron is present as bicarbonate, it acts on soap solutions like the analogous lime and magnesia compounds, producing even worse results. In wool scouring, cotton bleaching, and other processes requiring the use of alkaline carbonates, ferric oxide is precipitated on the fibre. A yellowish tinge is communicated to bleached fabrics, and to dye bright and light colours is rendered almost out of the question. You may always suspect iron to be present in water flowing from or obtained directly out of old coal pits, iron mines, or from places abounding in iron and aluminous shales. Moreover, you sometimes, or rather generally, find that surface water draining off moorland districts, and passing over ochre beds, contains iron, and on its way deposits on the beds of the streamlets conveying it, and on the stones, red or brown oxide of iron. All water of this kind ought to be avoided in dyeing and similar operations. The iron in water from old coal pits and shale deposits is usually present as sulphate due to the oxidation of pyrites, a sulphuret or sulphide of iron. Water from heaths and moorlands is often acid from certain vegetable acids termed "peaty acids." This acidity places the water in the condition of a direct solvent for iron, and that dissolved iron may cause great injury. If such water cannot be dispensed with, the best way is to carefully neutralise it with carbonate of soda; the iron is then precipitated as carbonate of iron, and can be removed. _Contamination of Water by Factories._--You may have neighbours higher up the stream than yourselves, and these firms may cast forth as waste products substances which will cause immense waste and loss. Amongst these waste products the worst are those coming from chemical works, |
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