The Chemistry of Hat Manufacturing - Lectures Delivered Before the Hat Manufacturers' Association by Watson Smith
page 50 of 178 (28%)
page 50 of 178 (28%)
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into two portions--a furnace for burning the sulphur, and a chamber for
receiving the vapours. The system was thus developed into the one followed at the present time. The sulphur, or, in most cases, cupreous iron pyrites (a combination of iron and copper with sulphur), is burned in specially constructed kilns or furnaces, and the hot gases, consisting essentially of sulphur dioxide with the excess of air, pass through flues in which are placed cast-iron "nitre pots" containing a mixture of nitre (sodium nitrate) and vitriol. The gases thus become mixed with nitrous fumes or gaseous oxides of nitrogen, and, after cooling, are ready for mixing with steam or water spray in the lead chambers in which the vitriol is produced. These oxides of nitrogen enable the formation of sulphuric acid to take place more quickly by playing the part of oxygen-carriers. Sulphuric acid is formed by the union of oxygen with sulphur dioxide and water; the oxides of nitrogen combine with the oxygen of the air present in the chambers, then give up this oxygen to the sulphur dioxide and water or steam to form sulphuric acid, again combine with more oxygen, and so on. The exact processes or reactions are of course much more complicated, but the above represents what is practically the ultimate result. It is evident that the gases leaving the last lead chamber in which the formation of vitriol is effected, must still contain nitrous fumes, and it becomes a matter of importance to recover them, so that they can be used over again. To effect this object, use is made of the solubility of nitrous fumes in strong vitriol. The gases from the last lead chamber of the series are passed through what is called a Gay-Lussac tower (the process was invented by the eminent French chemist Gay-Lussac), which is a tower made of lead, supported by a wooden framework, and filled with coke or special stoneware packing, over which strong vitriol is caused to flow. The vitriol dissolves the nitrogen oxides, and so-called "nitrous vitriol" flows out at the base of the tower. The recovery of the |
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