The Chemistry of Hat Manufacturing - Lectures Delivered Before the Hat Manufacturers' Association by Watson Smith
page 51 of 178 (28%)
page 51 of 178 (28%)
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nitrogen compounds from the nitrous vitriol is effected in Glover towers
(the invention of John Glover of Newcastle), which also serve to concentrate to some extent the weak acid produced in the lead chambers, and to cool the hot gases from the sulphur burners or pyrites kilns. The weak chamber acid is mixed with the nitrous vitriol from the Gay-Lussac tower, and the mixture is pumped to the top of the Glover tower, which is of similar construction to the Gay-Lussac tower, but is generally packed with flints. This Glover tower is placed between the sulphur burners or pyrites kilns and the first lead chamber. The nitrous vitriol passing down the tower meets the hot gases from the kilns, and a threefold object is effected: (1) The nitrous fumes are expelled from the nitrous vitriol, and are carried into the chambers, to again play the part of oxygen-carriers; (2) the weak chamber acid which was mixed with the nitrous vitriol is concentrated by the hot kiln gases; and (3) the hot gases themselves are cooled. The acid from the Glover tower is purified by special treatment--for example, the arsenic may be removed, after precipitation with sulphuretted hydrogen, in the form of insoluble arsenic sulphide,--and the purified acid is concentrated by heating in glass or platinum vessels. A considerable amount of sulphuric acid is now made by the so-called "contact process," in which sulphur dioxide and oxygen unite to form sulphuric acid in presence of a heated "contact" substance, usually some form of finely-divided platinum. _Nitric Acid._--This acid is usually prepared by distilling a mixture of sodium nitrate and vitriol in cast-iron retorts or pots, the nitric acid being collected in stoneware vessels connected one with another, or, as is more generally the case at the present time, in condensing apparatus consisting of stoneware pipes or coils cooled by water. The effluent |
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