The Chemistry of Hat Manufacturing - Lectures Delivered Before the Hat Manufacturers' Association by Watson Smith
page 73 of 178 (41%)
page 73 of 178 (41%)
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is so harmless to the fibre, and is easily driven off on steaming, etc.
A further reason is that from the solution of acetate of iron or alumina, basic acetates are very easily precipitated on heating, and are thus readily deposited in the fibre. _Mordanting and Fixing Basic Colours._--Now let us ask ourselves a very important question. Suppose we have a colour or dyestuff, such as Magenta, which is of a basic character, and not of an acid or phenolic character like the colours Alizarin, Hæmatein (logwood), or carminic acid (cochineal), and we wish to fix this basic dyestuff on the tissue. Can we then use "red liquor" (acetate of alumina), acetate of iron, copperas, etc.? The answer is, No; for such a process would be like trying to combine base with base, instead of base with acid, in order to form a salt. Combination, and so precipitation, would not take place; no lake would be formed. We must seek for an acid or acid body to use as mordant for our basic colour, and an acid or acid body that will form an insoluble precipitate or colour-lake with the dyestuff. An acid much used, and very valuable for this purpose, is tannic acid. The tannate of rosaniline (colour principle of Magenta) is a tolerably insoluble lake, which can be precipitated by Magenta from a solution of tannate of soda, the Magenta being capable of displacing the soda. But tannic acid, alone, does not form very fast lakes with Magenta and the other basic dyestuffs, and so a means of rendering these lakes more insoluble is needed. It is found that tannic acid and tartar emetic (a tartrate of antimony and potash) yield a very insoluble compound, a tannate of antimony. Perchloride of tin, in a similar manner, yields insoluble tannate of tin with tannic acid. These insoluble compounds, however, have sufficient acid-affinity left in the combined tannic acid to unite also with the basic aniline colours, forming very fast or insoluble colour lakes. This principle is extensively used in practice to fix |
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