The Chemistry of Hat Manufacturing - Lectures Delivered Before the Hat Manufacturers' Association by Watson Smith
page 74 of 178 (41%)
page 74 of 178 (41%)
![]() | ![]() |
|
basic aniline colours, especially on cotton. We should first soak the
piece of cotton in a solution of tannic acid, and then pass it into a solution, say, of tartar emetic, when the tannic acid will be firmly fixed, as tannate of antimony, on the cotton. We then dip the mordanted piece of cotton into the colour bath, containing, for instance, Magenta, and it is dyed a fine red, composed of a tannate of antimony and Magenta. You now see, no doubt, the necessity of sharply discriminating between two classes of colouring matters, which we may term _colour acids_ and _colour bases_ respectively. There are but few acids that act like tannic acid in fixing basic aniline dyestuffs, but oleic acid and other fatty acids are of the number. A curious question might now be asked, namely: "Could the acid colour Alizarin, if fixed on cotton cloth, combine with a basic aniline colour, _e.g._ Aniline Violet, and act as a mordant for it, thus fixing it?" The answer is, "Certainly"; and thus an Alizarin Purple would be produced, whilst if Magenta were used in place of Aniline Violet, an Alizarin Red of a crimson tone would result. _Chrome Mordanting of Wool and Fur._--In studying this subject I would recommend a careful perusal of the chapter on "Mordants" in J.J. Hummel's book, entitled _The Dyeing of Textile Fabrics_, and pages 337 to 340 of Bowman's work on _The Wool-Fibre_. In the treatment of wool or fur with bichrome (potassium bichromate) we start with an acid salt, a bichromate (K_{2}Cr_{2}O_{7}) and a strong oxidising agent, and we finish with a basic substance, namely, oxide of chromium, in the fibres of the wool or fur. If we desire to utilise the whole of the chromic acid in our mordanting liquor, we must add to it some sulphuric acid to set free the chromic acid from the potassium with which it is combined. Bichromate of potash with sulphuric acid gives |
|