The Chemistry of Hat Manufacturing - Lectures Delivered Before the Hat Manufacturers' Association by Watson Smith
page 80 of 178 (44%)
page 80 of 178 (44%)
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them will dye vegetable fibres like cotton and linen directly. Almost
all substantive colours may, however, be fixed on cotton and linen by first preparing or mordanting those vegetable fibres. Silk, wool, fur, etc., act like fibre and mordant together, for they absorb and fix the substantive colours firmly. In our experiments we saw that turmeric is one of the few substantive colours fixing itself on both cotton and wool, without any aid from a mordant or fixing agent. Magenta was also a substantive colour, but Alizarin was certainly not one of this class. _Adjective Dyestuffs._--Some of these substances are definitely coloured bodies, but in some of them the colour is of no consequence or value, and is quite different and distinct from the colour eventually formed on the fibre, which colour only appears in conjunction with a special mordant; but, again, some of them are not coloured, and would not colour the fibre directly at all, only in conjunction with some mordant. All the polygenetic colours are, of course, comprised in this class, for example Alizarin and logwood (Hæmatein), whilst such monogenetic colours as annatto and turmeric are substantive, for they will fix themselves without a mordant on cotton and wool. The adjective colours can be conveniently subdivided into--(_a_) those existing in nature, as logwood (Hæmatein) and Cochineal; (_b_) those artificially formed from coal-tar products, as Alizarin (madder), Gallein, etc. _Mineral and Pigment Dyestuffs._--These colours are insoluble in water and alcohol. They are either fixed on the fibre by mechanical means or by precipitation. For example, you use blacklead or plumbago to colour or darken your hats, and you work on this pigment colour by mechanical means. I will show you by experiment how to fix a coloured insoluble pigment in the fibre. I take a solution of acetate of lead (sugar of lead), and to it I add some solution of bichrome (potassium bichromate). |
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