An Introduction to Chemical Science by Rufus Phillips Williams
page 90 of 262 (34%)
page 90 of 262 (34%)
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refining Au and Ag, making alum, blacking, vitriols, glucose,
mineral waters, ether, indigo, madder, nitroglycerine, gun- cotton, parchment, celluloid, etc., etc. FUMING SULPHURIC ACID. 95. Nordhausen or Fuming Sulphuric Acid, H2S207 used in dissolving indigo and preparing coal-tar pigments, is made by distilling FeSO4. 4FeSO4 + H2O = H2S207 + 2Fe203 + 2S02. This was the original sulphuric acid. It is also formed when S03 is dissolved in H2SO4. When exposed to the air, S03 escapes with fuming. CHAPTER XX. AMMONIUM HYDRATE. 96. Preparation of Bases.--We have seen that many acids are made by acting on a salt of the acid required, with a stronger acid. This is the direct way. The following experiments will show that bases may be prepared in a similar way by acting on salts of the base required with other bases, which we may regard as stronger than the ones to be obtained. 97. Preparation of NH4OH and NH3. Experiment 57.--Powder 10 g. ammonium chloride, NH4Cl, in a mortar and mix with 10 g. calcium hydrate, Ca(OH)2; recently slaked lime is the best. Cover with water in a flask, and connect with Woulff bottles, as for making HCl (Fig. 22); heat the flask for fifteen |
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