An Introduction to Chemical Science by Rufus Phillips Williams
page 91 of 262 (34%)
page 91 of 262 (34%)
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minutes or more. The experiment may be tried on a smaller scale
with a t.t. if desired. The reaction is: 2NH4Cl + Ca(OH)2 = CaCl2 + 2NH4OH. NH4OH is broken up into NH3, ammonia gas, and water. NH4OH = NH3 + H2O. These pass over into the first bottle, where the water takes up the NH3, for which it has great affinity. One volume of water at 0° will absorb more than 1000 volumes of NH3. Thus NH4OH may be called a solution of NH3, in H2O. Write the reaction. Experiment 58.--Powder and mix 2 or 3 g. each of ammonium nitrate, NH4NO3, and Ca(OH)2; put them into a t.t., and heat slowly. Note the odor. 2NH4NO3 + Ca(OH)2 = ? 98. Tests. Experiment 59.--(1) Generate a little of the gas in a t.t., and note the odor. (2) Test the gas with wet red litmus paper. (3) Put a little HCl into an e.d., and pass over it the fumes of NH3 from a d.t. Note the result, and write the equation. (4) Fill a small t.t. with the gas by upward displacement; then, while still inverted, put the mouth of the t.t. into water. Explain the rise of the water. (5) How might NH4Cl be obtained from the NH4OH in the Woulff bottles? (6) Test the liquid in each bottle with red litmus paper. (7) Add some from the first bottle to 5 or 10 cc. of a solution of FeSO4 or FeCl2, and look for a ppt. State the reaction. 99. Formation.--Ammonia, hartshorn, exists in animal and vegetable compounds, in salts, and, in small quantities, in the |
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