Acetylene, the Principles of Its Generation and Use by F. H. Leeds;W. J. Atkinson Butterfield
page 58 of 592 (09%)
page 58 of 592 (09%)
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through (10/011) = 9 deg. C., or, which comes to the same thing, will heat 9
kilos, of steel through 1 deg. C.; and similarly, 1 large calorie will raise 4 kilos. of calcium carbide 1 deg. C. in temperature, or 1 kilo. 4 deg. C. The fact that a definite quantity of heat is manifested when a known weight of calcium carbide is decomposed by water is only typical; for in every chemical process some disturbance of heat, though not necessarily of sensible (or thermometric) character, occurs, heat being either absorbed or set free. Moreover, if when given weights of two or more substances unite to form a given weight of another substance, a certain quantity of heat is set free, precisely the same amount of heat is absorbed, or disappears, when the latter substance is decomposed to form the same quantities of the original substances; and, _per contra_, if the combination is attended by a disappearance of heat, exactly the same amount is liberated when the compound is broken up into its first constituents. Compounds are therefore of two kinds: those which absorb heat during their preparation, and consequently liberate heat when they are decomposed--such being termed endothermic; and those which evolve heat during their preparation, and consequently absorb heat when they are decomposed--such being called exothermic. If a substance absorbs heat during its formation, it cannot be produced unless that heat is supplied to it; and since heat, being a form of motion, is equally a form of energy, energy must be supplied, or work must be done, before that substance can be obtained. Conversely, if a substance evolves heat during its formation, its component parts evolve energy when the said substance is being produced; and therefore the mere act of combination is accompanied by a facility for doing work, which work may be applied in assisting some other reaction that requires heat, or may be usefully employed in any other fashion, or wasted if necessary. Seeing that there is a tendency in nature for the steady dissipation of energy, it follows that an exothermic substance is stable, for it tends to remain as it is |
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