Acetylene, the Principles of Its Generation and Use by F. H. Leeds;W. J. Atkinson Butterfield
page 59 of 592 (09%)
page 59 of 592 (09%)
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unless heat is supplied to it, or work is done upon it; whereas,
according to its degree of endothermicity, an endothermic substance is more or less unstable, for it is always ready to emit heat, or to do work, as soon as an opportunity is given to it to decompose. The theoretical and practical results of this circumstance will be elaborated in Chapter VI., when the endothermic nature of acetylene is more fully discussed. A very simple experiment will show that a notable quantity of heat is set free when calcium carbide is brought into contact with water, and by arranging the details of the apparatus in a suitable manner, the quantity of heat manifested may be measured with considerable accuracy. A lengthy description of the method of performing this operation, however, scarcely comes within the province of the present book, and it must be sufficient to say that the heat is estimated by decomposing a known weight of carbide by means of water in a small vessel surrounded on all sides by a carefully jacketed receptacle full of water and provided with a sensitive thermometer. The quantity of water contained in the outer vessel being known, and its temperature having been noted before the reaction commences, an observation of the thermometer after the decomposition is finished, and when the mercury has reached its highest point, gives data which show that the reaction between water and a known weight of calcium carbide produces heat sufficient in amount to raise a known weight of water through a known thermometric distance; and from these figures the corresponding number of large calories may easily be calculated. A determination of this quantity of heat has been made experimentally by several investigators, including Lewes, who has found that the heat evolved on decomposing 1 gramme of ordinary commercial carbide with water is 0.406 large calorie. [Footnote: Lewes returns his result as 406 calories, because he employs the "small calorie." The small calorie is |
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