A System of Instruction in the Practical Use of the Blowpipe - Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic Combinations by Anonymous
page 19 of 359 (05%)
page 19 of 359 (05%)
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If the oxide of a metal is brought into the luminous portion of the flame produced as above, so that the flame envelopes the substance perfectly, the access of air is prevented. The partially consumed gases have now a strong affinity for oxygen, under the influence of the intense heat of that part of the flame. The substance is thus deprived of a part, or the whole, of its oxygen, and becomes _reduced_ according to the strength of the affinity which the substance itself has for oxygen. If the reduction of a substance is undertaken on platinum, by fusion with a flux, and if the oxide is difficult to reduce, the reduction will be completely effected only in the luminous part of the flame. But if a substance be reduced on charcoal, the reduction will take place in the blue part of the flame, as long as the access of air is cut off; but it is the luminous part of the flame which really possesses the greatest reducing power. The following should be observed in order to procure a good reduction flame: The wick should not be too long, that it may make a smoke, nor too short, otherwise the flame will be too small to produce a heat strong enough for reduction. The wick must be free from all loose threads, and from charcoal. The blast should be continued for a considerable time without intermission, otherwise reduction cannot be effected. For the purpose of acquiring practice, the student may fuse the oxide |
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