Scientific American Supplement, No. 288, July 9, 1881 by Various
page 7 of 160 (04%)
page 7 of 160 (04%)
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operations are verified by Mr. Muentz as follows: He distills in the same
apparatus three to four gallons of chemically pure distilled water, and ascertains positively that under these conditions iodine and carbonate of soda give absolutely no reaction. Finally, to complete the demonstration and to ascertain the approximate quantity of alcohol contained in natural waters, he undertakes the double fractional distillation of a certain quantity of pure water to which he has previously added a one-millionth part of alcohol. Under these circumstances the iodine and carbonate of soda give a precipitate of iodoform exactly similar to that obtained by treating natural waters. [Illustration: Fig. 3.--IODOFORM CRYSTALS OBTAINED DIRECTLY (greatly magnified).] [Illustration: FIG. 4,--IODOFORM CRYSTALS OBTAINED WITH RAIN WATER.] In the case of arable soil, Mr. Muentz stirs up a weighed quantity of the material to be analyzed in a certain proportion of water, distills it in the smaller of the two apparatus, and detects the alcohol by means of the same operation as before. [Illustration: FIG. 5.--IODOFORM CRYSTALS OBTAINED WITH SNOW WATER.] The formation of iodoform by precipitation under the action of iodine and carbonate of soda is a very sensitive test for alcohol. Iodoform has sharply defined characters which allow of its being very easily distinguished. Its crystalline form, especially, is entirely typical, its color is pale yellowish, and, when it is examined under the microscope, it is seen to be in the form of six-pointed stars precisely like the crystalline form of snow. Mr. Muentz has not been contented to |
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