Scientific American Supplement, No. 324, March 18, 1882 by Various
page 61 of 143 (42%)
page 61 of 143 (42%)
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atoms of the individual elements. If we accept these two propositions,
it follows that hydrogen can be replaced atom for atom by other elements not only by the hydrogens but by alkali metals, etc. Hydrogen is, it may here be remarked, an element of unique character; not only can it be replaced by the elements of the widely different classes represented by chlorine and sodium, but it is the terminal of the series of paraffins, C_{n}H_{2n}; C_{3}H_{6}, C_{2}H_{4}, H_{2}. The third proposition which must be taken for granted is, that the groups of elements, C_{2}H_{5}, CH_{3}, behave as elements, and that these radicals, ethyl, methyl, etc., do not suffer decomposition in many chemical reactions. Now as to valency or atomicity, accepting the received atomic weights of the elements, it is certain that there are at least four distinct types of hydrogen compounds represented by ClH, OH_{2}, NH_{3}, CH_{4}. The recognition of these types, and their relations to each other as types, was one of the most important and best assured advances made in theoretical chemistry. When we compare the formula of water with that of hydrochloric acid, we find that there is twice as much hydrogen combined with one atom of oxygen as there is combined with one atom of chlorine; and in a great many other instances, we find that we can replace two atoms of chlorine by one atom of oxygen, so that we get an idea of the exchangeable value of these elements, and we say that one atom of oxygen is worth two of chlorine, or is bivalent; similarly, nitrogen is said to be trivalent. The meaning attached to the word "valency," is simply one of interchangeability, just as we say a penny is worth two halfpennies or four farthings. The question next arises, is the valency of an element fixed or variable? If the word be defined as above, it is absolutely certain that the valency varies. Thus, tin may be trivalent, SnCl_{2}, or tetravalent, SnCl_{4}. Accordingly elements have been classed as monads, dyads, triads, etc. The lecturer objected most |
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