Scientific American Supplement, No. 324, March 18, 1882 by Various
page 62 of 143 (43%)
page 62 of 143 (43%)
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strongly to the word "atomicity;" he could not conceive of one atom
being more atomic than another; he could understand the atomicity of a molecule or the equivalency of an atom, but not the atomicity of an atom; the expression seemed to him complete nonsense. He next considered the possibility of assigning a fixed limit to this valency or adicity of an atom, and concluded that the adicity was not absolutely fixed, but was fixed in relation to certain elements, e.g., C never combines with more than four atoms of H; O never more than two atoms of H, etc. The adicity of an element when combined with two or more elements is usually higher than when combined with only one, e.g., NH_{3}, NH_{4}Cl. The term "capacity of saturation," may be used as a synonym for adicity, if care be taken to distinguish it from other kinds of saturation, such as an acid with an alkali, etc. Adicity is, however, quite distinct from combining force; the latter is indicated by the amount of heat evolved in the combination. The lecturer then proceeded to criticise a statement commonly found in text books, that chemical combination suppresses altogether the properties of the combining bodies. The reverse of this statement is probably true. To take the case commonly given of the combination of copper and sulphur when heated; this is good as far as it goes, but there are numerous instances, as ClI, SSe, etc., where the original properties and characters of the combining elements do not completely disappear. The real statement is that the original properties of the elements disappear more or less, and least when the combination is weak and attended with the evolution of a slight amount of heat, and in every case some properties are left which can be recognized. So with reference to the question of atomic and molecular combination, as atomic combination does not necessarily produce change, it does not differ in this respect from what is usually called molecular combination. |
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