Scientific American Supplement, No. 324, March 18, 1882 by Various
page 63 of 143 (44%)
page 63 of 143 (44%)
![]() | ![]() |
|
The lecturer then referred to an important difference in the adicity of chlorine and oxygen. Chlorine can combine with methyl or ethyl singly. Oxygen can combine with both and hold them together in one molecule. The recognition of this fundamental difference between chlorine and oxygen, this formation of double oxides as opposed to single chlorides, marks an epoch in scientific chemistry. The lecturer then considered the subject of chemical formulae; it is the bounden duty of every formula to express clearly the number of atoms of each kind of elementary matter which enters into the constitution of the molecule of the substance. A formula may do much more than this. If we attempt to express too much by a complex formula we may veil the number of atoms contained in it. This difficulty may be avoided by using two formulae, a synoptic formula giving the number of atoms present, and a complex formula perhaps covering half a page, giving the constitution of the molecule. But between the purely synoptic formula and the very elaborate formula there are others--contracted formulae--which labor under the disadvantage, as a rule, of being one-sided, and so create a false impression as to the nature of the substance. Thus, for instance, to take the formula of sulphuric acid, H_{2}SO_{4}. This suggests that all the oxygen is united to the S; (HO)_{2}SO_{2} suggests that two atoms of hydroxyl exist in the molecule; then, again, we might write the formula HSO_{2}OH, or H_{2}OSO_{3}. All of these are justifiable, and each might be useful to explain certain reactions of sulphuric acid, but to use one only creates a false impression. The only plan is to use them variously and capriciously, according to the reaction to be explained. Again, ethyl acetate may be written-- H_{3}C\ |
|